Alias - Season 5 Episode 12

One month later, with Sydney on maternity leave, she gets forced back into the field when her old enemy, Anna Espinosa, returns after she's secretly sprung from prison by Peyton who gives her a job offer to work for Prophet Five whose leaders have secretly contact with Sloan to get him to set up Sydney in exchange for getting the cure for Nadia. Anna decides that to get at Sydney is that she needs to go through her friends, leading to Anna to abduct Will Tippen. Sydney, along with APO, is forced to try to find Anna and save Will before he's killed unaware that Prophet Five has bigger plans for Syd, to take a sample of her DNA.